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FORMULATION & ACTIVE INGREDIENT:
SHIRLAN is a suspension concentrate containing 500 g/l (38.4% w/w) fluazinam
Control of Foliar Blight (
) and protection against Tuber Blight in potatoes.
WATER VOLUME AND BCPC SPRAY QUALITY:
200–500 litres per hectare as a MEDIUM spray quality.
MAXIMUM INDIVIDUAL DOSE (litres product/ha):
MAXIMUM TOTAL DOSE (litres product/ha/crop):
Other Specific Restrictions:
A MINIMUM OF 5 DAYS MUST BE OBSERVED BETWEEN APPLICATIONS AT THE 300 ML PRODUCT/HA RATE OR A MINIMUM OF 7 DAYS AT THE 400 ML PRODUCT/HA RATE
BUFFER ZONE RESTRICTIONS:
LERAP Category B.
FOR USE ONLY AS:
AN AGRICULTURAL FUNGICIDE
This product label is compliant with the CPA Voluntary Initiative (VI) guidance.
The following tank mixes have been tested for physical compatibility with SHIRLAN at recommended rates of use and will mix in the sprayer tank. No tests have been undertaken on crop safety or product performance, therefore use is at the user’s own risk. Syngenta UK Ltd will support the physical compatibility of 2 or 3-way tank mixes of SHIRLAN with any of the fungicides, herbicides or insecticides listed. For further information on compatibilities, contact Syngenta UK Ltd on 0800 1696058.
Curzate M WG
HALLMARK with ZEON TECHNOLOGY
Syngenta UK Ltd will support the tank mixing of any of the named trace elements with an existing 2 or 3-way tank mix including SHIRLAN. Syngenta UK Ltd advise that the trace element part of the tank mix is added to the sprayer tank last with constant agitation and the mixture is sprayed without delay.
Nutrel Fastmix K-Man*
Nutrel Fastmix Manganese*
Nutrel Fastphyte Complete*
Nutrel Fastphyte High K*
Nutrel Maxman 400*
Nutrel Nutrichel CaB*
Nutrel Nutrifast Catalyst*
Yara Vita Bortrac
Yara Vita Caliphos
Yara Vita Croplift
Yara Vita Liquid Manganese
Yara Vita Magflo 300
Yara Vita MagPhos
Yara Vita Mantrac
Yara Vita Mantrac DF
Yara Vita Phosamco
Yara Vita Photrel
Yara Vita Seniphos
Yara Vita Stopit
Yara Vita Sulphur F3000
Yara Vita Zintrac
*All Nutrel trace elements are supported/tested by Nutrel.
Before using any tank mixture, consult and comply with the recommendations of the partner products. Each product should be added separately to the bulk of the water in the spray tank and thoroughly mixed before adding the next chemical. Always use constant agitation of the sprayer tank during mixing, transportation and application. Spray immediately.
Use plant protection products safely. Always read the label and product information before use.
DIRECTIONS FOR USE
IMPORTANT: This information is approved as part of the Product Label. All instructions within this section must be carefully read in order to obtain safe and successful use of this product.
ADDITIONAL ADVICE FOR OPERATORS
• SHIRLAN may cause transient skin reaction in a small number of sensitive individuals.
• Do not come in contact with spray drift. Ensure spraying is carried out under good conditions and that the sprayer is adjusted to minimise drift.
• Do not allow contact of contaminated clothing with unprotected skin.
• Do not allow contact between contaminated sprayer parts and unprotected skin. Ensure sprayer is washed down daily.
• Wash all protective clothing (coveralls) regularly, preferably daily, when working with SHIRLAN.
• When entering crops do not allow contact of unprotected skin with treated foliage.
• People who have been sensitised by SHIRLAN should not use or have further contact with the product.
SHIRLAN is an agricultural fungicide for the control of Foliar Blight (
) and protection against Tuber Blight in potatoes.
BACKGROUND TO POTATO BLIGHT CONTROL
Late blight (
) is potentially a devastating disease of potatoes. In commercial production, a season long
policy is essential. First of all ensure that other control methods are being satisfactorily applied:
1. Prevent re-growth on potato dumps.
2. Destroy all groundkeepers.
3. Plant disease-free seed.
4. Use generous soil ridges to protect tubers.
Integrate this approach with a fungicide programme:
In first and second early potato crops, particularly those grown in the same locality as main crop potatoes, an adequate and full blight protection programme should be applied right up to harvesting or haulm desiccation. This will protect the early crop while helping to reduce disease risk to later crops.
Disease prevention programmes require regular and season-long fungicide use to limit foliar blight development. However, as an effective fungicide programme will preserve leaf area there may be more risk of infecting tubers at harvest, particularly during “heavy” blight years. Completion of the control programme should therefore include a complete haulm desiccant. Lifting of the crop should not take place for at least 10 days after
of the haulm. Crops intended for storage should not be lifted while there is any green tissue
on the leaves or stem bases.
Blight Risk Assessment
The risk of disease is affected by
(during the crop life) and
– Spread of disease occurs under warm, humid conditions. Preferably use a reliable decision support system to determine what frequency of fungicide treatment is appropriate and fungicide type required.
Note: Blight forecasting has often been based on the occurrence of “Smith Periods”. A “Smith Period” is a 48 hour period in which the minimum temperature is 10°C or more and the relative humidity exceeds 90% for at least 11 hours during the first 24 hours and for at least 11 hours again during the final 24 hours. However, any period of warm, humid weather increases blight risk.
– Locations with the highest probability of blight problems are:
• Areas of the country where extensive main crop or early production takes place e.g. East Anglia, the South West or the West.
• Areas where climatic conditions that encourage disease development occur on a frequent basis. e.g. the South West, the West and the Fens.
CROP SPECIFIC INFORMATION
1. Initial Application
SHIRLAN is a protectant fungicide and therefore the spray programme must start BEFORE blight enters the crop.
Irrespective of crop growth stage, commence spraying at the first blight warning or when local weather conditions are favourable for the disease,
whichever is the sooner
. Otherwise, in the absence of weather conducive to disease development, the first application should be made just before foliage of adjacent plants begins to meet IN THE ROWS.
2. Repeat Applications
Intervals between applications of SHIRLAN MUST be reduced as blight risk increases, so that
of the crop can be maintained, as follows:
“Low risk” situations
– applications should be made as a precautionary measure, before conditions conducive to blight development have occurred – APPLY AT 14 DAY INTERVALS
“High risk” situations
– following two warm, humid days or in irrigated crops – APPLY AT 7–10 DAY INTERVALS.
“Severe risk” situations
– during continued warm, humid weather and when blight is in nearby crops, potato dumps or volunteer plants – APPLY 300 ml AT 5–7 DAY INTERVALS OR 400 ml AT 7 DAY INTERVALS AS APPROPRIATE, ACCORDING TO BLIGHT WARNINGS AND DISEASE PREDICTION SYSTEMS
N.B. Potato blight fungicides may not give complete protection when the disease risk is severe. However, disease development will be delayed dramatically with a well timed spray programme.
Do not apply more than a maximum total dose of 3 litres product/ha/crop.
3. For protection against Tuber Blight
To reduce the risk of problems with tuber blight at harvest SHIRLAN should be used regularly at the recommended intervals from full canopy development to complete haulm desiccation.
Rates of Use
Apply 300–400 ml/ha of SHIRLAN at each treatment.
Crops grown for processing
Consult processor before use.
MIXING AND SPRAYING
Apply SHIRLAN in 200 to 500 litres of water per hectare. Use adequate water to ensure complete coverage of the foliage and stems, increasing the volume as haulm growth progresses, particularly in dense crops and under high or severe blight risk conditions.
1. Application Equipment:
Apply SHIRLAN through tractor-drawn or mounted, conventional hydraulic crop spraying equipment.
2. Sprayer Preparation:
Ensure that the sprayer is clean and calibrated correctly, to give even application. Apply at the recommended water volumes using a MEDIUM quality spray (as defined by British Crop Protection Council guidelines).
3. Spray Pressure:
at least 2 bar.
Before mixing SHIRLAN, first part fill the spray tank with clean water and commence agitation. Then, shake the SHIRLAN container and add the required amount of product to the sprayer using a filling device (e.g. induction bowl, probe etc), or otherwise by direct addition to the spray tank.
Wash out empty container thoroughly and add washings to the sprayer. Preferably use an integrated pressure rinsing device, otherwise manually rinse the container three times. DO NOT RE-USE CONTAINER FOR ANY PURPOSE.
Agitate spray tank contents thoroughly whilst filling and throughout the spraying operation.
Do not leave the spray liquid in the sprayer for long periods (such as during meal breaks or overnight).
Disease control may be reduced if strains of pathogen less sensitive to SHIRLAN develop.
This product is to be used only in accordance with the recommendations and instructions given on the label provided with this pack. Use in any other circumstances is entirely at the user’s risk.
PROTECT FROM FROST
SHAKE WELL BEFORE USE
(a) Operator protection
Engineering control of operator exposure must be used where reasonably practicable in addition to the following personal protective equipment:
WEAR SUITABLE PROTECTIVE CLOTHING (COVERALLS), SUITABLE PROTECTIVE GLOVES AND FACE PROTECTION (FACESHIELD) when handling the concentrate.
WEAR SUITABLE PROTECTIVE CLOTHING (COVERALLS) AND SUITABLE PROTECTIVE GLOVES when handling contaminated surfaces.
However engineering controls may replace personal protective equipment if a COSHH assessment shows they provide an equal or higher standard of protection.
TAKE OFF IMMEDIATELY all contaminated clothing.
WASH CONCENTRATE from skin and eyes immediately.
WASH ALL PROTECTIVE CLOTHING thoroughly after use, especially the insides of gloves.
WASH HANDS AND EXPOSED SKIN before meals and after work.
IF YOU FEEL UNWELL seek medical advice (show label where possible).
(b) Environmental protection
To protect aquatic organisms respect an unsprayed buffer zone to surface water bodies in line with LERAP requirements.
DO NOT ALLOW DIRECT SPRAY from horizontal boom sprayers to fall within 5 metres of the top of the bank of a static or flowing water-body, unless a Local Environmental Risk Assessment for Pesticides (LERAP) permits a narrower buffer zone, or within 1 metre of the top of a ditch which is dry at the time of application. DO NOT ALLOW DIRECT SPRAY from hand-held sprayers to fall within 1 metre of the top of the bank of a static or flowing water-body. Aim spray away from
This product qualifies for inclusion within the Local Environmental Risk Assessment for Pesticides (LERAP) scheme. Before each spraying operation from a horizontal boom sprayer, either a LERAP must be carried out in accordance with PSD published guidance or the statutory buffer zone must be maintained. The results of the LERAP must be recorded and kept available for 3 years.
DO NOT CONTAMINATE SURFACE WATERS OR DITCHES with chemical or used container.
Do not clean application equipment near surface water. Avoid contamination via drains from farmyards and roads
(c) Storage and disposal
KEEP IN ORIGINAL CONTAINER, tightly closed in a safe place.
DO NOT RE-USE CONTAINER FOR ANY PURPOSE.
RINSE CONTAINER THOROUGHLY by using an integrated pressure rinsing device or manually rinsing three times. Add washings to sprayer at time of filling and dispose of safely.
THE (COSHH) CONTROL OF SUBSTANCES HAZARDOUS TO HEALTH REGULATIONS MAY APPLY TO THE USE OF THIS PRODUCT AT WORK
FOR USE ONLY AS AN AGRICULTURAL FUNGICIDE
MAXIMUM INDIVIDUAL DOSE:
400 ml product/ha
MAXIMUM TOTAL DOSE:
3 litres product/ha/crop
Other specific restrictions:
A minimum of five days must be observed between applications at the 300 ml product/ha rate or a minimum of seven days at the 400 ml product/ha rate.
READ THE LABEL BEFORE USE. USING THIS PRODUCT IN A MANNER THAT IS INCONSISTENT WITH THE LABEL MAY BE AN OFFENCE. FOLLOW THE CODE OF PRACTICE FOR USING PLANT PROTECTION PRODUCTS.
Syngenta UK Limited, CPC4, Capital Park, Fulbourn, Cambridge, CB21 4XE
Tel: Cambridge (01223) 883400
In case of toxic or transport emergency ring 01484 538444 any time.
SECTION 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY OR UNDERTAKING
Identification of the substance or preparation
Company Syngenta UK Ltd
CPC4, Capital Park, Fulbourn, Cambridge, CB21 4XE
Phone (01223) 883400
Fax (01223) 882195
Emergency Phone +44 (0)1484 538444 (24h)
SECTION 2. HAZARDS IDENTIFICATION
Irritating to eyes. May cause sensitisation by skin contact. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
RISK PHRASES (R):
23, 36, 43, 50/53
poly(oxy-1,2-ethanediyl), alphasulpho-omega-[tris(1-phenylethyl) phenoxy]-, ammonium salt
RISK PHRASES (R):
For the full text of the R phrases mentioned in this section, see section 16.
SECTION 4. FIRST AID MEASURES
Have the product container, label or Material Safety Data Sheet with you when calling the Syngenta emergency number, a Poison Control Centre or physician, or going for treatment.
Remove to fresh air. If breathing is irregular or stopped, administer artificial respiration. Keep patient warm and at rest. Call a physician or Poison Control Centre immediately.
Take off all contaminated clothing immediately. Wash off immediately with plenty of water. If skin irritation persists, call a physician. Wash contaminated clothing before re-use.
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses. Immediate medical attention is required.
If swallowed, seek medical advice immediately and show this container or label. Do NOT induce vomiting.
There is no specific antidote available. Treat symptomatically.
SECTION 5. FIRE FIGHTING MEASURES
Suitable extinguishing media
Extinguishing media – small fires:
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Extinguishing media – large fires:
Use alcohol-resistant foam or water spray.
Extinguishing media which must not be used for safety reasons:
Do not use a solid water stream as it may scatter and spread fire.
Specific hazards during fire fighting:
As the product contains combustible organic components, fire will produce dense black smoke containing hazardous products of combustion (see section 10). Exposure to decomposition products may be a hazard to health.
Special protective equipment for fire fighters:
In the event of fire, wear full protective clothing and self-contained breathing apparatus. .
Do not allow run-off from fire fighting to enter drains or water courses. Cool closed containers exposed to fire with water spray.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Refer to protective measures listed in sections 7 and 8.
Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitary sewer system.
Methods for cleaning up:
Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13).
If the product contaminates rivers and lakes or drains inform respective authorities.
SECTION 7. HANDLING AND STORAGE
Advice on safe handling:
No special protective measures against fire required. Avoid contact with skin and eyes. When using, do not eat, drink or smoke. For personal protection see section 8.
Requirements for storage areas and containers: No special storage conditions required. Keep containers tightly closed in a dry, cool and well-ventilated place. Keep out of the reach of children. Keep away from food, drink and animal feeding stuffs.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
8 h TWA
Containment and/or segregation is the most reliable technical protection measure if exposure cannot be eliminated. The extent of these protection measures depends on the actual risks in use. If airborne mists or vapours are generated, use local exhaust ventilation controls. Assess exposure and use any additional measures to keep airborne levels below any relevant exposure limit. Where necessary, seek additional occupational hygiene advice.
PERSONAL PROTECTIVE EQUIPMENT
When using this product refer to the label for details. In all other cases, use the following Personal Protective Equipment:
The use of technical measures should always have priority over the use of personal protective equipment. When selecting personal protective equipment, seek appropriate professional advice. Personal protective equipment should be certified to appropriate standards.
No personal respiratory protective equipment normally required. A particulate filter respirator may be necessary until effective technical measures are installed.
Chemical resistant gloves should be used. Gloves should be certified to an appropriate standard. Gloves should have a minimum breakthrough time that is appropriate to the duration of exposure. The breakthrough time of gloves varies according to the thickness, material and manufacturer. Gloves should be changed when breakthrough is suspected. Suitable material: Nitrile rubber
If eye contact is possible, use tight-fitting chemical safety goggles.
Skin and body protection:
Assess the exposure and select chemical resistant clothing based on the potential for contact and the permeation/penetration characteristics of the clothing material. Wash with soap and water after removing protective clothing. Decontaminate clothing before re-use, or use disposable equipment (suits, aprons, sleeves, boots, etc.). Wear as appropriate: impervious protective suit.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Miscible in/with water.
15 to 25 mPas at 20ºC
SECTION 10. STABILITY AND REACTIVITY
Hazardous decomposition products:
Combustion or thermal decomposition will evolve toxic and irritant vapours.
None known. Hazardous polymerisation does not occur. Stable under normal conditions.
SECTION 11. ECOLOGICAL INFORMATION
ELIMINATION INFORMATION (PERSISTENCE AND DEGRADABILITY)
Stability in water:
Fluazinam is not persistent in water.
Stability in soil:
Fluazinam is very to moderately persistent in soil.
Fluazinam is immobile in soil.
Toxicity to Fish:
(rainbow trout), 0.061, 96 h.
Toxicity to Aquatic Invertebrates:
(water flea), 0.119 mg/l, 48 h.
Toxicity to Algae:
(green algae), > 0.534 mg/l, 96 h.
SECTION 12. TOXICOLOGICAL INFORMATION
Acute Oral Toxicity LD50, rat:
> 2000 mg/kg
Acute Dermal Toxicity LD50, rat:
Acute Inhalation Toxicity LC50, rat:
>1.15 mg/l, 4 h
Eye Irritation, rabbit:
Skin Irritation, rabbit:
Non-irritant. Derived from components.
Sensitisation, guinea pig:
Sensitising. Remarks: Based on test results obtained with similar product.
Long Term Toxicity:
Did not show carcinogenic, teratogenic or mutagenic effects in animal experiments.
SECTION 13. DISPOSAL CONSIDERATIONS
Do not contaminate ponds, waterways or ditches with chemical or used containers. Do not dispose of waste into sewer. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations.
Empty remaining contents. Triple rinse containers. Empty containers should be taken for local recycling or waste disposal. Do not re-use empty containers.
SECTION 14. TRANSPORT INFORMATION
UN no.: 3082
Packaging Group: III
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., (FLUAZINAM)
Marine pollutant: Yes
SECTION 15. REGULATORY INFORMATION
N DANGEROUS FOR THE ENVIRONMENT
Risks phrases (R)
36 Irritating to eyes.
43 May cause sensitisation by skin contact.
50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety phrases (S)
2 Keep out of the reach of children.
13 Keep away from food, drink and animal feeding stuffs.
20/21 When using do not eat, drink or smoke.
24/25 Avoid contact with skin and eyes.
35 This material and its container must be disposed of in a safe way.
36/37 Wear suitable protective clothing and gloves.
46 If swallowed, seek medical advice immediately and show this container or label.
57 Use appropriate containment to avoid environmental contamination.
To avoid risks to man and the environment, comply with the instructions for use.
SECTION 16. OTHER INFORMATION
Use plant protection products safely. Always read the label and product information before use.
Product approval number: MAPP 10573.
Based upon SDS Version 2 with local amendment, release date 27/10/09.
Text of R phrases mentioned in Section 2
Toxic by inhalation.
Irritating to eyes.
May cause sensitisation by skin contact.
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
A 500 g/litre SC formulation containing fluazinam. A foliar applied fungicide for the control of Foliar Blight and protection against Tuber Blight in potatoes
Maximum application rate: 400 ml product/ha
Maximum total dose: 3 litres product/ha/crop
WILDLIFE, MAMMALS AND BIRDS
SHIRLAN is not classified as
‘Harmful to game and wildlife’
MAMMALS AND BIRDS
No risk management is necessary to protect mammals and birds. SHIRLAN is of low toxicity to mammals and birds. The risk to wild mammals and birds feeding on treated areas is low due to the limited amount of residues likely to be consumed.
No risk management is necessary as SHIRLAN poses a low risk to honey bees. There is no requirement to avoid application of the product when bees may be foraging on flowering weeds in and around treated areas.
NON-TARGET INSECTS AND OTHER ARTHROPODS
No risk management is necessary. SHIRLAN poses a minimal risk to the range of arthropod species commonly found in and around treated fields e.g. ground beetles, Lycosid spiders, predatory mites and parasitic wasps.
SHIRLAN is classified as ‘Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment’.
SHIRLAN is highly toxic to certain aquatic invertebrates such as
and fish and is also moderately toxic to algae. SHIRLAN shows rapid degradation in sediments of aquatic systems indicating a low risk. Care must be taken to ensure that surface waters or ditches are not contaminated with the product or used container.
Risk management is essential. SHIRLAN can be used safely providing care is taken to prevent spray drift reaching surface waters. The following risk management practices must be carried out in order to ensure that there is adequate protection for aquatic species.
‘Do not allow direct spray from ground based vehicle mounted/drawn sprayers to fall within 5m of surface waters or ditches; direct spray away from water’
LERAP Category B. Buffer zones may be reduced (see LERAP Guidelines)
SOIL AND GROUNDWATER, EARTHWORMS AND SOIL MICRO-ORGANISMS
SOIL AND GROUNDWATER
Fluazinam is very to moderately persistent in soil, depending on the soil type. Fluazinam is absorbed to soil and is therefore of low mobility. Due to its limited mobility in soil there is a negligible risk of groundwater contamination.
No risk management is necessary. SHIRLAN is of low toxicity to earthworms. Field studies have also demonstrated that SHIRLAN is unlikely to have any adverse effects on earthworm populations in the long term.
No risk management is necessary. No effects on soil microbial processes were found and so the risk is considered to be low.
Care should always be taken to minimise the drift of pesticides into conservation headlands, beetle banks and field boundaries such as hedgerows, which may provide an important habitat for wild flowers, non-target insects and other wildlife.
Use plant protection products safely. Always read the label and product information before use.
Care must be taken to minimise the risk of surface water contamination from farmyard and field sources.
For further information about the environmental profile of this product contact:
Company: Syngenta UK Ltd
Address: CPC4, Capital Park, Fulbourn, Cambridge CB21 4XE
Telephone: 0800 1696058
Fax: 01223 882195
This Environmental Information Sheet was prepared in accordance with CPA Guidance Notes Version 3.
© copyright of Syngenta
The SHIRLAN Trademark is the property of a Syngenta Group Company
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